Recent questions tagged chemical-reaction-engineering

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The outlet concentration $C_A$ of a plug flow reactor $\text{(PFR)}$ is controlled by manipulating the inlet concentration $C_{A 0}$. The following transfer function desc...
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Catalytic reforming is commonly used in the petroleum industry to improve fuel quality. The undesirable reaction in the catalytic reforming of naphtha isHydrocracking of ...
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A control system on the jacket side of a reactor is shown in the figure. Pressurized water flows through the jacket to cool the reactor. The heated water flashes in the b...
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The reaction $A \rightarrow B$ is carried out isothermally on a porous catalyst. The intrinsic reaction rate is $kC_{A}^{2}$, where $k$ is the rate constant and $C_{A}$ i...
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In an enzymatic reaction, an inhibitor $(I)$ competes with the substrate $(S)$ to bind with the enzyme $(E)$, thereby reducing the rate of product $(P)$ formation. The co...
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Consider the process flowsheet in the figure. An irreversible liquid-phase reaction $A \rightarrow B$ (reaction rate $-r_{A} = 164 \:x_{A}\text{ kmol }m^{-3}\:h^{-1}$) oc...
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An equimolar binary mixture is to be separated in a simple tray-distillation column. The feed rate is $50\text{ kmol min}^{-1}$ . The mole fractions of the more volatile ...
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Consider the process in the figure. The liquid phase elementary reactions $$A + B \rightarrow P \:\:\:\: -r_{B1} = k_{1}\:x_{A}\:x_{B}$$ $$P + B \rightarrow S \:\:\:\: -r...
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An elementary irreversible liquid-phase reaction, $2A \rightarrow B$, is carried out under isothermal conditions in a $1\:m^{3}$ ideal plug flow reactor $\text{(PFR)}$ as...
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An elementary irreversıble gas-phase reaction, $A \rightarrow B + C$, is carried out at fixed temperature and pressure in two separate ideal reactors: $(i)$ a $10\:m^{3}$...
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An elementary irreversible liquid-phase reaction, $2P \overset{k}{\rightarrow}Q$, where the rate constant $k = 2\:L\:\text{mol}^{-1}\:\text{min} ^{-1}$, takes place in an...
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Ethylene adsorbs on the vacant active sites $V$ of a transition metal catalyst according to the following mechanism.If $N_T, N_V$ and $N_{C_2H_4}$ denote the total number...
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The following homogeneous liquid phase reactions are at equilibrium,The values of rate constants are given by: $k_1 = 0.1 s^{-1}$, $k_{-1}=0.2 s^{-1}, k_2 = 1 s^{-1}, k_{...
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The following isothermal autocatalytic reaction $$ A +B \longrightarrow 2B \quad\quad\quad(-r_A)=0.1C_AC_B(\text{mol } L^{-1} s^{-1})$$is carried out in an ideal continuo...
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Reactant $A$ decomposes to products $B$ and $C$ in the presence of an enzyme in a well-stirred batch reactor. The kinetic rate expression is given by$$-r_A = \dfrac{0.01C...
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The following homogeneous, irreversible reaction involving ideal gases, $$A \longrightarrow B+C \quad\quad\quad(-r_A)=0.5C_A (\text{mol L}^{-1} s^{-1})$$ is carried out i...
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The decomposition of acetaldehyde $(X)$ to methane and carbon monoxide follows four-step free radical mechanism. The overall rate of decomposition of $X$ is $$-r_X=k_2 \b...
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Equilibrium data for a binary mixture of $E$ and $F$ at two different pressure is shown in the figure.It is desired to process a feed containing $80 \text{ mol } \% E$ an...
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A feed stream containing pure species $L$ flows into a reactor, where $L$ is partly converted to $M$ as shown in the figure.The mass flow rate of the recycle stream is $2...
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An elementary liquid phase reversible reaction $P \leftrightarrows Q$ is carried out in an ideal continuous stirred tank reactor (CSTR) operated at steady state. The rate...
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An exothermic, aqueous phase, irreversible, first order reaction, $Y \rightarrow Z$ is carried out in an ideal continuous stirred tank reactor (CSTR) operated adiabatical...
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The liquid phase irreversible reactions, $P \xrightarrow[]{k_1} Q$ and $P \xrightarrow[]{k_2} R$, are carried out in an ideal continuous stirred tank reactor (CSTR) opera...
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A catalytic gas phase reaction $P \rightarrow Q$ is conducted in an isothermal packed bed reactor operated at steady state. The reaction is irreversible and second order ...
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In a laboratory experiment, a unit pulse input of tracer is given to an ideal plug flow reactor operating at steady state with a recycle ratio, $R=1$. The exit age distri...
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The square of Thiele modulus, $M_{T}$, is given by $M_{T}^2 = \dfrac{L^2k}{D_{eff}}$, where $L$ is the characteristic length of the catalyst pellet, $k$ is the rate const...
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Pure gas $\textbf{P}$ is being absorbed into a liquid. The dissolved $\textbf{P}$ undergoes an irreversible reaction in the liquid film. The reaction is first order with ...
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The desired liquid-phase reaction$D+E\overset{k_{1}}{\rightarrow}F \:\:\:\:\:\:\:\:\:r_{F}=k_{1}\:C_{D}^{2}\:C_{E}^{0.3}$is accompanied by an undesired side reaction$D+E\...
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For a first order reaction in a porous spherical catalyst pellet, diffiusional effects are most likely to lower the observed rate of reaction for slow reaction in a pell...
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The elementary, irreversible liquid-phase, parallel reactions, $2A\rightarrow D$ and $2A\rightarrow U$, take place in an isothermal non-ideal reactor. The $C$-curve measu...
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A first-order irreversible liquid phase reaction $A\rightarrow B\left ( k=0.1\:min^{-1} \right )$ is carried out under isothermal, steady state conditions in the followin...
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The elementary liquid-phase irreversible reactions$A\overset{k_{1}=0.4\: min^{-1}}{\rightarrow}B\overset{k_{2}=0.1\:min^{-1}}{\rightarrow}C$take place in an isothermal id...
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The elementary irreversible gas-phase reaction $A\rightarrow B+C$ is carried out adiabatically in an ideal $CSTR$ (Continuous-Stirred Tank Reactor) operating at 10 $atm$....
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Consider the reactor-separator-recycle process operating under steady state conditions as shown in the figure. The reactor is an ideal Continuous-Stirred Tank Reactor ($C...
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The following reaction rate curve is shown for a reaction $A{\rightarrow}P$. Here, $(-r_{A})$ and $X_{A}$ represent reaction rate and conversion, respectively. The feed i...
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Consider a first order catalytic reaction in a porous catalyst pellet.Given $R$ – characteristics length of the pellet; $D_{e}$ – effective diffusivity; $k_{c}$ – mass tr...
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For a solid-catalyzed gas phase reversible reaction, which of the following statements is ALWAYS TRUE?Adsorption is rate-limitingDesorption is rate-limitingsolid catalyst...
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The purpose of methanation reaction used in ammonia plants is toremove $CO$ as it is catalyst poisonincrease the amount of hydrogenremove sulphur as it is a catalyst pois...
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The $C$-curve measured during a pulse tracer experiment is shown below. In the figure, $C(t)$ is the concentration of the tracer measured at the reactor exit in mol/liter...
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The following gas-phase reaction is carried out in a constant-volume isothermal batch reactor$$A+B{\rightarrow}R+S$$The reactants $A$ and $B$ as well as the product $S$ a...
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Hydrogen iodide decomposes through the reaction $2HI\leftrightharpoons H_{_{2}}+I_{2}$. The value of the universal gas constant $R$ is $8.314 \:J\:mol^{-1}K^{-1}$. The ac...