Recent questions tagged chemical-reaction-engineering

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For a non-catalytic homogeneous reaction $A\rightarrow B$, the rate expression at $300\:K$ is $-r_{A}$$\left (mol\; m^{-3} s^{-1}\right )=\frac{10C_{A}}{1+5C_{A}}$...
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The variations of the concentration $\left ( C_{A} ,C_{R}\:and\:C_{S}\right )$ for three species $\left ( A,R\:and\:S \right )$ with time, in an isothermal homogeneous ba...
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The liquid phase reversible reaction $A\rightleftharpoons B$ is carried out in an isothermal $CSTR$ operating under steady state conditions. The inlet stream does not con...
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A liquid phase irreversible reaction$A{\rightarrow}B$ is carried out in an adiabatic $CSTR$ operating under steady state conditions. The reaction is elementary and follow...
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A porous pellet with $Pt$ dispersed in it is used to carry out a catalytic reaction. Following two scenarios are possible.$Scenario\:1$ : $Pt$ present throughout the pore...
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A $CSTR$ has a long inlet pipe. A tracer is injected at the entrance of the pipe. The $E$-curve obtained at the exit of the $CSTR$ is shown in the figure below.Assuming p...
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A catalytic reforming plant produces hydrogen and benzene from cyclohexane by de-hydro aromatisation. In order to increase the production of hydrogen, the owner plans to ...
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For a gas phase cracking reaction $A{\rightarrow}B+C$ at $300^{\circ}$, the Gibbs free energy of the reaction at this temperature is $\Delta G^{\circ}=-2750$ $J$/mol. The...
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Which of the following can change if only the catalyst is changed for a reaction system?Enthalpy of reactionActivation energyFree energy of the reactionEquilibrium consta...
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For which reaction order, the half-Iife of the reactant is half of the full lifetime (time for $100 \%$ conversion) of the reactant ?Zero orderHalf orderFirst orderSecond...
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An irreversible, homogeneous reaction $A{\rightarrow}$ products, has the rate expression:Rate = $\frac{2C_{A}^{2}+0.1C_{A}}{1+50C_{A}}$, where $C_{A}$ is the concentratio...
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A binary feed consisting of $25$ mol$\%$ liquid and $75$ mol$\%$ vapour is separated in a staged distillation column. The mole fraction of the more volatile component in ...
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Consider two steady isothermal flow configurations shown schematically as Case $I$ and Case $II$ below. In Case $I$, a $CSTR$ of volume $V_{1}$ is followed by a $PFR$ of ...
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A catalyst slab of half-thickness $L$ (the width and length of the slab $>>\:L$) is used to conduct thefirst order reaction $A{\rightarrow} B$. At $450\: K$, the Thiele m...
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The impulse response to a tracer pulse experiment or a flow reactor is given below :In the above figure, $C$ is the exit tracer concentration. The corresponding $E$ or $E...
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An isothermal steady state mixed flow reactor $(CSTR)$ of $1\:m^{3}$ volume is used to carry out the first order liquid-phase reaction $A{\rightarrow}$ products. Fresh fe...
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Determine the correctness or otherwise of the following Assertion $[a]$ and Reason $[r]$Assertion: Significant combustion of coke takes place only if it is heated at high...
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Match the following$$\begin{array}&&\textbf{Group I} & \textbf{Group II} \\ &\text{P. Tank in series model} & \text{I. Non-isothermal reaction}\\&\text{Q. Liquid-liquid ...
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A vapour phase catalytic reaction $(Q+R{\rightarrow}S)$ follows Rideal mechanism ($R$ and $S$ are not absorbed). Initially, the mixture contains only the reactants in equ...
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A homogenous reaction $(R{\rightarrow}P)$ occurs in a batch reactor. The conversion of the reactant $R$ is $67\%$ after $10$ minutes and $80\%$ after $20$ minutes. The ra...
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The vessel dispersion number for an ideal $CSTR$ is $-1$$0$$1$$\infty$
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In oder to achieve the same conversion under identical reaction conditions and feed flow rate for a non-autocatalytic reaction of positive order, the volume of an ideal $...
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Match the following $$\begin{array}&&\textbf{Group I} & \textbf{Group II} \\ &\text{P. $\left [ \frac{\partial G}{\partial n_{i}} \right ]_{T,P,n_{\int =i}}$} & \text{I....
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Liquid reactant A decomposes as follows A $\rightarrow$ R r${_R} $= k${_1}$C$^{2}$${_A}$ k${_1}$ = 0.5m$^{3}$/mol-s...
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Liquid reactant A decomposes as follows A $\rightarrow$ R r${_R} $= k${_1}$C$^{2}$${_A}$ k${_1}$ = 0.5m$^{3}$/mol-s...
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The vapor liquid equilibrium relation for an ideal binary system is given by y*${_A}$ = $\frac{\alpha{_A}{_B}x{_A}}{...
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A first order liquid phase reaction is carried out isothermally at a steady state in a CSTR and 90% conversion is attained. With the same inlet conditions and for the sam...
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The gas phase decomposition of azomethane to give ethane and nitrogen takes place according to the following sequence of elementary reactions.(CH${_3}){_2}$N${_2}$ + (CH$...
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The overall rates of an isothermal catalytic reaction using spherical catalyst particles of diameters 1 mm and 2 mm are $r_A$$_1$ and $r_A$$_2$ (in mol (kg-catalyst)$^{-1...
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An isothermal liquid phase zero order reaction A $\rightarrow$ B (k = 0.5 mol/m$^{3}$ -s) is carried out in a batch reactor. The initial concentration of A is 2 mol/m$^{3...
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The exit age distribution for a reactor is given by E(t) = $\delta$(t-4), where t is in seconds. A first order liquid phase reaction (k = 0.25 s$^{-1}$) is carried out in...
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The first order liquid phase reaction $A \rightarrow P$ is conducted isothermally in a plug flow reactor of $5$ liter volume. The inlet volumetric flow rate is $1$ liter/...
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The plug flow reactor is replaced by 3 mixed flow reactors in series, each of 2.0 liters volume. The exact conversion of A (in %) is35.952.573.794.8
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Match the process in Group I with the catalyst in Group II Group I ...
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The reaction A${_l}{_i}{_q}$ +B${_g}{_a}{_s}$ $\rightarrow$C${_l}{_i}{_q}$ +D${_g}{_a}{_s}$, is carried out in a rector followed by a separator as shown below ...
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An equimolar mixture of $A$ and $B$ (A being more volatile) is flash distilled continuously at a feed rate of $100 \text{ kmol/h}$, such that the liquid product contains ...
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The elementary reversible exothermic gas-phase reaction A + 3B $\rightleftharpoons$ 2Cis to be conducted in a non-i...
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The rate-controlling step for the solid-catalyzed irreversible reaction $ A + B \longrightarrow C$is known ...
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A bed of spherical glass beads (density $3000 \text{ kg/m$^3$}$, diameter $1\:\text{mm}$, bed porosity $0.5$) is to be fluidized by a liquid of density $1000 \text{ kg/m$...
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The main unit processes used for the production of hydrogen from natural gas are stream reforming $(\text{SR})$, pressure swing adsorption $(\text{PSA})$, low temperature...