Recent questions in Chemical Reaction Engineering

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An irreversible gas phase reaction $2 \textbf{P} \rightarrow 4 \textbf{Q} + \textbf{R}$ is conducted in an isothermal and isobaric batch reactor. Assume ideal gas behavio...
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The decomposition of acetaldehyde $(X)$ to methane and carbon monoxide follows four-step free radical mechanism. The overall rate of decomposition of $X$ is $$-r_X=k_2 \b...
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A feed stream containing pure species $L$ flows into a reactor, where $L$ is partly converted to $M$ as shown in the figure.The mass flow rate of the recycle stream is $2...
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An elementary liquid phase reversible reaction $P \leftrightarrows Q$ is carried out in an ideal continuous stirred tank reactor (CSTR) operated at steady state. The rate...
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An exothermic, aqueous phase, irreversible, first order reaction, $Y \rightarrow Z$ is carried out in an ideal continuous stirred tank reactor (CSTR) operated adiabatical...
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The liquid phase irreversible reactions, $P \xrightarrow[]{k_1} Q$ and $P \xrightarrow[]{k_2} R$, are carried out in an ideal continuous stirred tank reactor (CSTR) opera...
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A catalytic gas phase reaction $P \rightarrow Q$ is conducted in an isothermal packed bed reactor operated at steady state. The reaction is irreversible and second order ...
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In a laboratory experiment, a unit pulse input of tracer is given to an ideal plug flow reactor operating at steady state with a recycle ratio, $R=1$. The exit age distri...
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The square of Thiele modulus, $M_{T}$, is given by $M_{T}^2 = \dfrac{L^2k}{D_{eff}}$, where $L$ is the characteristic length of the catalyst pellet, $k$ is the rate const...
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The desired liquid-phase reaction$D+E\overset{k_{1}}{\rightarrow}F \:\:\:\:\:\:\:\:\:r_{F}=k_{1}\:C_{D}^{2}\:C_{E}^{0.3}$is accompanied by an undesired side reaction$D+E\...
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For a first order reaction in a porous spherical catalyst pellet, diffiusional effects are most likely to lower the observed rate of reaction for slow reaction in a pell...
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The elementary, irreversible liquid-phase, parallel reactions, $2A\rightarrow D$ and $2A\rightarrow U$, take place in an isothermal non-ideal reactor. The $C$-curve measu...
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A first-order irreversible liquid phase reaction $A\rightarrow B\left ( k=0.1\:min^{-1} \right )$ is carried out under isothermal, steady state conditions in the followin...
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The elementary liquid-phase irreversible reactions$A\overset{k_{1}=0.4\: min^{-1}}{\rightarrow}B\overset{k_{2}=0.1\:min^{-1}}{\rightarrow}C$take place in an isothermal id...
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The elementary irreversible gas-phase reaction $A\rightarrow B+C$ is carried out adiabatically in an ideal $CSTR$ (Continuous-Stirred Tank Reactor) operating at 10 $atm$....
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The following reaction rate curve is shown for a reaction $A{\rightarrow}P$. Here, $(-r_{A})$ and $X_{A}$ represent reaction rate and conversion, respectively. The feed i...
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Consider a first order catalytic reaction in a porous catalyst pellet.Given $R$ – characteristics length of the pellet; $D_{e}$ – effective diffusivity; $k_{c}$ – mass tr...
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For a solid-catalyzed gas phase reversible reaction, which of the following statements is ALWAYS TRUE?Adsorption is rate-limitingDesorption is rate-limitingsolid catalyst...
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The $C$-curve measured during a pulse tracer experiment is shown below. In the figure, $C(t)$ is the concentration of the tracer measured at the reactor exit in mol/liter...
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The following liquid phase second-order reaction is carried out in an isothermal $CSTR$ steady steady$$A{\rightarrow}R\:\:\:\:\:(-r_{A})=0.005C_{A}^{2}\:mol/m^{3}.hr$$whe...
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The following gas-phase reaction is carried out in a constant-volume isothermal batch reactor$$A+B{\rightarrow}R+S$$The reactants $A$ and $B$ as well as the product $S$ a...
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For a non-catalytic homogeneous reaction $A\rightarrow B$, the rate expression at $300\:K$ is $-r_{A}$$\left (mol\; m^{-3} s^{-1}\right )=\frac{10C_{A}}{1+5C_{A}}$...
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The variations of the concentration $\left ( C_{A} ,C_{R}\:and\:C_{S}\right )$ for three species $\left ( A,R\:and\:S \right )$ with time, in an isothermal homogeneous ba...
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Hydrogen iodide decomposes through the reaction $2HI\leftrightharpoons H_{_{2}}+I_{2}$. The value of the universal gas constant $R$ is $8.314 \:J\:mol^{-1}K^{-1}$. The ac...
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The liquid phase reversible reaction $A\rightleftharpoons B$ is carried out in an isothermal $CSTR$ operating under steady state conditions. The inlet stream does not con...
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A liquid phase irreversible reaction$A{\rightarrow}B$ is carried out in an adiabatic $CSTR$ operating under steady state conditions. The reaction is elementary and follow...
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A porous pellet with $Pt$ dispersed in it is used to carry out a catalytic reaction. Following two scenarios are possible.$Scenario\:1$ : $Pt$ present throughout the pore...
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A $CSTR$ has a long inlet pipe. A tracer is injected at the entrance of the pipe. The $E$-curve obtained at the exit of the $CSTR$ is shown in the figure below.Assuming p...
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A catalytic reforming plant produces hydrogen and benzene from cyclohexane by de-hydro aromatisation. In order to increase the production of hydrogen, the owner plans to ...
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Which of the following can change if only the catalyst is changed for a reaction system?Enthalpy of reactionActivation energyFree energy of the reactionEquilibrium consta...
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For which reaction order, the half-Iife of the reactant is half of the full lifetime (time for $100 \%$ conversion) of the reactant ?Zero orderHalf orderFirst orderSecond...
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An irreversible, homogeneous reaction $A{\rightarrow}$ products, has the rate expression:Rate = $\frac{2C_{A}^{2}+0.1C_{A}}{1+50C_{A}}$, where $C_{A}$ is the concentratio...
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A typical batch filtration cycle consists of filtration followed by washing. One such filtration unit operating at constant pressure difference first filters a slurry dur...
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Consider two steady isothermal flow configurations shown schematically as Case $I$ and Case $II$ below. In Case $I$, a $CSTR$ of volume $V_{1}$ is followed by a $PFR$ of ...
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A catalyst slab of half-thickness $L$ (the width and length of the slab $>>\:L$) is used to conduct thefirst order reaction $A{\rightarrow} B$. At $450\: K$, the Thiele m...
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The impulse response to a tracer pulse experiment or a flow reactor is given below :In the above figure, $C$ is the exit tracer concentration. The corresponding $E$ or $E...
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An isothermal steady state mixed flow reactor $(CSTR)$ of $1\:m^{3}$ volume is used to carry out the first order liquid-phase reaction $A{\rightarrow}$ products. Fresh fe...
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A homogenous reaction $(R{\rightarrow}P)$ occurs in a batch reactor. The conversion of the reactant $R$ is $67\%$ after $10$ minutes and $80\%$ after $20$ minutes. The ra...
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A vapour phase catalytic reaction $(Q+R{\rightarrow}S)$ follows Rideal mechanism ($R$ and $S$ are not absorbed). Initially, the mixture contains only the reactants in equ...
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Match the following$$\begin{array}&&\textbf{Group I} & \textbf{Group II} \\ &\text{P. Tank in series model} & \text{I. Non-isothermal reaction}\\&\text{Q. Liquid-liquid ...