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​​​​​If $k$ is the mass transfer coefficient and $D_{v}$ is the molecular diffusivity, which one of the following statements is NOT CORRECT with respect to mass transfer theories?

  1. For Film theory, $k \propto D_{v}$
  2. For Penetration theory, $k \propto D_{v}^{1 / 3}$
  3. For Surface Renewal theory, $k \propto D_{v}^{1 / 2}$
  4. For Boundary Layer theory, $k \propto D_{v}^{2 / 3}$

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