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A spherical storage vessel is quarter-filled with toluene. The diameter of the vent at the top of the vessel is $1/20^{th}$ of the diameter of the vessel. Under the steady state condition, the diffusive flux of toluene is maximum at 

  1. the surface of the liquid 
  2. the mid-plane of the vessel
  3. the vent
  4. a distance $20$ times the diameter of the vent away from the vent
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